Any control voltage / trigger etc is still just an electrical signal the same as an audio signal, however its worth bearing in mind that the instantaneous rise times and associated amplitudes of CV signals can cause certain DAC modules to behave sub-optimally.
Some interfaces may not have a big enough voltage swing for some CV formats as 10V peak to peak translates to about 13.2dBu; EVO 16 outputs are capable of 12dBu.
Expert Sleepers make some pretty useful ADAT to CV conversion modules that you may want to look into if integrating VCV rack and an EVO 16 with modular hardware.
https://www.expert-sleepers.co.uk/es3.html
More info:
https://vcvrack.com/manual/VoltageStandards#:~:text=Signals%20should%20typically%20be%2010,5%20V%20(bipolar%20CV).